Form

Forme (Fr), Forma (It), 結晶形 (Ja)

Definition

For a point group P a form is a set of all symmetrically equivalent "elements", namely:

• in vector space, a crystal form or face form is a set of all symmetrically equivalent faces;
• in point space, a point form is a set of all symmetrically equivalent points.

The polyhedron or polygon of a point form is dual to the polyhedron of the corresponding face form, where "dual" means that they have the same number of edges but the number of faces and vertices is interchanged. The inherent symmetry of a form is a point group C which either coincides with the generating point group P or is a supergroup of it.

Forms in point groups correspond to crystallographic orbits in space groups.

Wyckoff positions of forms

The number of possible forms of a point group is infinite. They are easily classified in terms of Wyckoff positions of point groups

• A Wyckoff position of a crystal form consist of all those crystal forms of a point group P for which the face poles are positioned on the same set of conhjugate symmetry elements of P
• A Wyckoff position of a point form consist of all those point forms of a point group P for which the points are positioned on the same set of conhjugate symmetry elements of P

Classification of forms

Forms are classified on the basis of their symmetry properties and of their orientation with respect to the symmetry elements of the point groups in which they occur.

General vs. special forms

A face is called general if only the identity operation transform the face onto itself. Each complete set of symmetrycally equivalent general faces is a general crystal form. The mulplicity (number of faces of the form) of a general form is the order of the point group P. In the stereographic projection, the poles of general faces do not lie on any symmetry element of P.

A point is called general if its site symmetry is 1. A general point form is a complete set of symmetrically equivalent general points.

A face is called special if it is transformed into itself by at least one symmetry operation of P, in addition to the identity. Each complete set of symmetrically equivalent special faces is called a special crystal form. The face symmetry of a special face is the group of symmetry operations that transforms this face onto itself; it is a subgroup of P. The multiplicity of a special form is the multiplicity of the general form divided by the order of the face-symmetry group. In the stereographic projection, the poles of special faces lie on symmetry elements of P.

A point is called special if its site symmetry is higher than 1. A special point form is a complete set of symmetrically equivalent special points. The multiplicity of a special point form is the multiplicity of the general from divided by the order of the site symmetry group and is the same as that of the corresponding special crystal form.

Characteristic vs. non-characteristis forms

A form is called characteristic if its inherent symmetry coincides with the generating point group P.

A form is called non-characteristic if its inherent symmetry is a supergroup of the generating point group P.

Basic vs. limiting forms

In a Wyckoff position, forms of different inherent symmetries may occur.

• Forms with the lowest inherent symmetry are called basic forms
• Forms of higher inherent symmetry are called limiting forms

Limiting forms always have the same multiplicity and oriented symmetry as the corresponding basic forms because they belong to the same Wyckoff position. The face poles (for face forms) or points (for point forms) of a limiting form lie on symmetry elements of a supergroup of the point group that are not symmetry elements of the point group itself.

Example

In the point group 4mm, the pyramid {h0l} has inherent symmetry C = 4mm and multiplicity 4; its face symmetry is .m. In the same group, the prism {100} has inherent symmetry C = 4/mmm and multiplicity 4; its face symmetry is again .m.

• For the pyramid, C = P and thus the form is characteristic. For the prism, C ⊃ P and thus the form is non-characteristic.
• Both forms lie on the mirrors perpendicular to the secondary symmetry directions; both forms are special.
• The prism can be seen as the limiting result of opening the pyramid at its vertex: the pyramid is the basic form, wheras the prism is a limiting form (the only one in this case). The face poles of the prism stay also on the mirror plane perpendicular to the fourfold axis which belong to C, supergroup of P, but not to P.

List of crystal (face) forms

47 or 48 forms exist, depending on whether the diedre is separated into sphenoid and dome or not. In parenthesis the inherent symmetry of the form.

Open forms

• Pedion ([math]\infty[/math]m)
• Pinacoid ([math]\infty[/math]m /m)
• Diedre (mm2)
• Rhombic prism (mmm)
• Rhombic pyramid (mm2)
• Trigonal pyramid (3m)
• Tetragonal pyramid (4mm)
• Hexagonal pyramid (6mm)
• Ditrigonal pyramid (3m)
• Ditetragonal pyramid (4mm)
• Dihaxagonal pyramid (6mm)
• Trigonal prism ([math]\bar62m[/math])
• Tetragonal prism (4/mmm)
• Hexagonal prism (6/mmm)
• Ditrigonal prism ([math]\bar62m[/math])
• Ditetragonal prism (4/mmm)
• Dihexagoanl prism (6/mmm)

Closed forms

• Rhombic disphenoid (222)
• Rhombic bipyramid (mmm)
• Trigonal bipyramid ([math]\bar62m[/math])
• Tetragonal bipyramid (4/mmm)
• Hexagonal bipyramid (6/mmm)
• Ditrigonal bipyramid ([math]\bar62m[/math])
• Ditetragonal bipyramid (4/mmm)
• Dihexagonal bipyramid (6/mmm)
• Tetragonal disphenoid ([math]\bar42m[/math])
• Rhombohedron ([math]\bar3m[/math])
• Tetragonal scalenohedron ([math]\bar42m[/math])
• Ditrigional scalenohedron ([math]\bar3m[/math])
• Tetragonal trapezohedron (422)
• Trigonal trapezohedron (32)
• Hexagonal trapezohedron (622)
• Tetardohedron or pentagono-tritetrahedron (23)
• Pentagonododecahedron ([math]m\bar3[/math])
• Diployd or Didodecahedron ([math]m\bar3[/math])
• Gyroedron or pentagonotrioctahedron (432)
• Tetrahedron ([math]\bar43m[/math])
• Tetragonotritetrahedron ([math]\bar43m[/math])
• Trigonotritedrahedron ([math]\bar43m[/math])
• Hexatetrahedron ([math]\bar43m[/math])
• Cube ([math]m\bar3m[/math])
• Octahedron ([math]m\bar3m[/math])
• Rhombododecahedron ([math]m\bar3m[/math])
• Trigonotrioctahedron ([math]m\bar3m[/math])
• Tetragonotrioctahedron ([math]m\bar3m[/math])
• Tetrahexahedron ([math]m\bar3m[/math])
• Hexaoctahedron ([math]m\bar3m[/math])

Note: the disphenoids are sometimes improperly called "tetrahedra"

See also

• Chapter 10 in the International Tables for Crystallography, Volume A