Difference between revisions of "Isomorphous crystals"
From Online Dictionary of Crystallography
BrianMcMahon (talk | contribs) m |
|||
| Line 1: | Line 1: | ||
<Font color="blue">Cristaux isomorphes </Font>(''Fr''). <Font color="red"> Isomorphe Kristalle </Font> (''Ge''). <Font color="green"> Cristales isomorfos</Font> (''Sp'').<Font color="black"> Cristalli isomorfi </Font>(''It'') | <Font color="blue">Cristaux isomorphes </Font>(''Fr''). <Font color="red"> Isomorphe Kristalle </Font> (''Ge''). <Font color="green"> Cristales isomorfos</Font> (''Sp'').<Font color="black"> Cristalli isomorfi </Font>(''It'') | ||
| − | |||
| Line 7: | Line 6: | ||
Two crystals are said to be isomorphous if (''a'') both have the same space group and unit-cell dimensions and (''b'') the types and the positions of atoms in both are the same except for a replacement of one or more atoms in one structure with different types of atoms in the other ([[isomorphous replacement]]), such as heavy atoms, or the presence of one or more additional atoms in one of them (''isomorphous addition''). Isomorphous crystals can form ''solid solutions''. | Two crystals are said to be isomorphous if (''a'') both have the same space group and unit-cell dimensions and (''b'') the types and the positions of atoms in both are the same except for a replacement of one or more atoms in one structure with different types of atoms in the other ([[isomorphous replacement]]), such as heavy atoms, or the presence of one or more additional atoms in one of them (''isomorphous addition''). Isomorphous crystals can form ''solid solutions''. | ||
| − | == History == The notion of isomorphism was discovered by Mitscherlich who found that the crystal forms of salts such as the hydrated potassium phosphates and arsenates or the hydrated potassium copper and iron sulfates were identical (1819, 1820). | + | == History == |
| + | |||
| + | The notion of isomorphism was discovered by Mitscherlich who found that the crystal forms of salts such as the hydrated potassium phosphates and arsenates or the hydrated potassium copper and iron sulfates were identical (1819, 1820). | ||
== See also == | == See also == | ||
Revision as of 14:20, 6 February 2012
Cristaux isomorphes (Fr). Isomorphe Kristalle (Ge). Cristales isomorfos (Sp). Cristalli isomorfi (It)
Definition
Two crystals are said to be isomorphous if (a) both have the same space group and unit-cell dimensions and (b) the types and the positions of atoms in both are the same except for a replacement of one or more atoms in one structure with different types of atoms in the other (isomorphous replacement), such as heavy atoms, or the presence of one or more additional atoms in one of them (isomorphous addition). Isomorphous crystals can form solid solutions.
History
The notion of isomorphism was discovered by Mitscherlich who found that the crystal forms of salts such as the hydrated potassium phosphates and arsenates or the hydrated potassium copper and iron sulfates were identical (1819, 1820).
See also
- Group isomorphism
- Section 2.4 of International Tables of Crystallography, Volume B