Wyckoff position

Position de Wyckoff (Fr). Wyckoff punktlage (Ge). Posizione di Wyckoff (It). ワイコフ位置 (Ja)

Definition

A Wyckoff position consists of all points X of a space group G for which the site-symmetry groups are conjugate subgroups of G.

Each Wyckoff positon of a space group is labelled by a letter which is called the Wyckoff letter.

The number of different Wyckoff position of each space group is finite, the maximal numbers being 9 for plane groups (realized in p2mm) and 27 for space groups (realized in Pmmm).

Wyckoff positions of point groups

By analogy to the Wyckoff positions of space groups, Wyckoff positions of point groups have been defined too: here the term "position" indicates the position of face poles (form face forms) or of points (for point forms) in the stereographic projection. Like in space groups, in point groups too each Wyckoff position is labelled by a Wyckoff letter.

History

The term Wykcoff position takes its origin from the first English collection of equivalent positions in space groups, which appeared in The analytical expression of the results of the theory of space groups by Ralph W.G. Wyckoff, published by Carnegie Institution of Washington (second edition, 1930), and which can be considered an ancestor of the International Tables of Crystallography.

See also

• crystallographic orbit
• form
• lattice complex
• point configuration
• stabilizer
• Wyckoff set
• Sections 8.3.2 and 10.1.2.2 of the International Tables of Crystallography, Volume A