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Difference between revisions of "Modulated crystal structure"

From Online Dictionary of Crystallography

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<Font color="blue">Structure cristalline modul&eacute;e</font> (''Fr''). <Font color="black">Struttura cristallina modulata </Font>(''It''). <Font color="purple"> 変調構造 </Font>(''Ja'').
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<font color="blue">Structure cristalline modul&eacute;e</font> (''Fr''). <font color="red">Modulierte Kristallstruktur</font> (''Ge''). <font color="black">Struttura cristallina modulata</font> (''It''). <font color="purple">変調構造</font> (''Ja''). <font color="green">Estructura cristalina modulada</font> (''Sp'').
  
 
== Definition ==
 
== Definition ==

Latest revision as of 12:58, 16 November 2017

Structure cristalline modulée (Fr). Modulierte Kristallstruktur (Ge). Struttura cristallina modulata (It). 変調構造 (Ja). Estructura cristalina modulada (Sp).

Definition

A modulated crystal structure is a density (or atom arrangement) that may be obtained from a density (or atom arrangement) with space-group symmetry by a finite density change (or finite displacement of each atom, respectively) that is (quasi)periodic. A function or a displacement field is periodic if it is invariant under a lattice of translations. Then its Fourier transform consists of δ-peaks on a reciprocal lattice that spans the space and is nowhere dense. A quasiperiodic function has a Fourier transform consisting of δ-peaks on a vector module of finite rank. This means that the peaks may be indexed with integers using a finite number of basis vectors. If the modulation consists of deviations from the basic structure in the positions, the modulation is displacive (see figure). When the probability distribution deviates from that in the basic structure the modulation is occupational.

BO01F05.gif

Model for a displacively modulated crystal structure. The basic structure is two-dimensional rectangular, with lattice constants a and b, the modulation wave vector is in the b-direction, the wavelength of the periodic modulation is λ such that λ/b is an irrational number.

See also