From Online Dictionary of Crystallography
Revision as of 04:11, 8 July 2015 by MassimoNespolo (precision)
Règle de priorité (Fr). Regola di priorità (It)
When more than one kind of symmetry element occurs for a given symmetry direction, the choice for defining the appropriate Hermann–Mauguin symbol for the space group is made in order of descending priority:
- m, e, a, b, c, n, d;
- rotation axes before screw axes of the same rotational order.
There are a few exceptions to this choice:
- For glide planes in centred monoclinic space groups, the priority rule is purposely not followed in order to bring out the relations between the three ‘cell choices’ given for each setting.
- For orthorhombic space groups, the priority rule is applied only to the ‘standard symbol’. The symbols for the other ﬁve settings are obtained from the standard symbol by the appropriate transformations, without invoking the priority rule again.
- Space-group types I222 and I212121 are two distinct types. Both contain parallel twofold rotation and screw axes and thus would receive the same symbol according to the priority rule. In I222, the three rotation axes and the three screw axes intersect, whereas in I212121 neither the three rotation axes nor the three screw axes intersect.
- For space groups of type No. 73, the standard symbol Ibca was adopted, instead of Ibaa according to the rule, because Ibca displays the equivalence of the three symmetry directions clearly.
- In tetragonal space groups with both a and b glide planes containing the  direction, the preference was given to b, as in P4bm.
- In cubic space groups where tertiary symmetry planes with glide components 1/2, 0, 0; 0, 1/2, 0; 0, 0, 1/2 and 1/2, 1/2 , 1/2 coexist, the tertiary symmetry element was called n in P groups (instead of a, b or c) but c in F groups, because these symmetry elements intersect the origin.
- Space groups of type I23 and I213 (199) are two distinct types of space groups. For this pair, the same arguments apply as given above for I222 and I212121.
Sections 18.104.22.168 of International Tables for Crystallography, Volume A