# Goldschmidt tolerance factor

### From Online Dictionary of Crystallography

Facteur de tolérance de Goldschmidt (*Fr*). Goldschmidtscher Toleranzfaktor (*Ge*). Fattore di tolleranza di Goldschmidt (*It*). Factor de tolerancia de Goldschmidt (*Sp*).

**Goldschmidt's tolerance factor** is a dimensionless number that measures the stability and distortion of crystal structures. Originally introduced to describe perovskite structure, tolerance factors are today also used for ilmenite. It can be used to calculate the compatibility of an ion with a crystal structure.

The Goldschmidt tolerance factor (*t*) is calculated from the ratio of the ionic radii:

[math]t={r_A+r_0 \over \sqrt{2}(r_B+r_0)}[/math] |

where *r*_{A} is the radius of the *A*-cation, *r*_{B} is the radius of the *B*-cation and *r*_{0} is the radius of the anion (usually oxygen).

In an ideal cubic perovskite structure the cell parameter *a* can be calculated from the atomic radii as

[math]a=\sqrt{2}(r_A+r_0)=2(r_B+r_0).[/math] | ||