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- Ewald sphere
- Extended X-ray absorption fine structure (EXAFS)
- Extinction symbol
- Extinctions
- F
- F(000)
- Factor group
- Family structure
- Fermi level
- Ferroics
- Fixed-point-free space group
- Flack parameter
- Flux
- Flux density
- Form
- Free R factor
- Friedel's law
- Friedel pair
- G
- Geometric crystal class
- Geometric element
- Gnomonic projection
- Goldschmidt tolerance factor
- Group
- Group homomorphism
- Group isomorphism
- Groupoid
- H
- H centred cell
- Habit
- Harker section
- Heavy-atom method
- Hemihedry
- Hemitropy
- Hermann-Mauguin symbols
- High energy resolution fluorescence detection (HERFD)
- Holohedry
- Hybrid input-output algorithm
- Hybrid twin
- I
- Image
- Incommensurate composite crystal
- Incommensurate magnetic structure
- Incommensurate modulated structure
- Inelastic X-ray scattering (IXS)
- Integral reflection conditions
- Interim Report of Working Group
- International Union of Crystallography
- Interplanar spacing
- Inversion twin